Donor–acceptor interaction-driven self-assembly of amphiphilic rod–coil molecules into supramolecular nanoassemblies
| Autor: | Tie Chen, Shengsheng Yu, Long Yi Jin, Yuntian Yang, Jingzhe Xu |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Materials science Supramolecular chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Micelle Acceptor 0104 chemical sciences Supramolecular polymers Crystallography chemistry Amphiphile Molecule General Materials Science Lamellar structure Self-assembly 0210 nano-technology |
| Zdroj: | Nanoscale. 9:17975-17982 |
| ISSN: | 2040-3372 2040-3364 |
| DOI: | 10.1039/c7nr05329k |
| Popis: | Rigid-flexible amphiphilic molecules consisting of an aromatic segment based on pyrene and biphenyl units and hydrophilic polyethylene oxide chains self-assemble into lamellar, hexagonal columnar, and two-dimensional columnar nanostructures in the bulk state. In aqueous solution, these molecules self-assemble into nanofibers, spherical micelles, and multilayer nanotubes, depending on the chain or rod length of the molecules. Notably, ordered nanostructures of supramolecular polymers, such as single-layer curving fragments, nanofibers, and nanosheets, were constructed through charge-transfer interactions between the nanoobjects and an electron-acceptor molecule, 2,4,5,7-tetranitrofluorenone. These experimental results reveal that diverse supramolecular morphologies can be controlled by tuning rod-coil molecular interactions or charge-transfer interactions between the donor and acceptor molecules. |
| Databáze: | OpenAIRE |
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