Compact CPL emitters based on a [2.2]paracyclophane scaffold: recent developments and future perspectives
| Autor: | Simon Felder, Marie-Leonie Delcourt, Damian Contant, Rafael Rodríguez, Ludovic Favereau, Jeanne Crassous, Laurent Micouin, Erica Benedetti |
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| Přispěvatelé: | Laboratoire de Chimie et de Biochimie Pharmacologiques et Toxicologiques (LCBPT - UMR 8601), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Agence Nationale de la Recherche (ANR PhotoChiraPhane), CNRS, IdEx Universite Paris Cite (pCpPhotoCat), Universite de Rennes 1, Ministere de l'Enseignement Superieur et de la Recherche, Xunta de Galicia, ANR-19-CE07-0001,PhotoChiraPhane,Synthèse et applications de catalyseurs photoredox à chiralité planaire dérivés du [2.2]paracyclophane(2019) |
| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Journal of Materials Chemistry C Journal of Materials Chemistry C, 2023, 11, pp.2053-2062. ⟨10.1039/d2tc04885j⟩ |
| ISSN: | 2050-7534 2050-7526 |
| DOI: | 10.1039/d2tc04885j |
| Popis: | International audience; Due to their unique three-dimensional framework and intriguing electronic properties, [2.2]paracyclophanes (pCps) have been employed over the years as building blocks in materials science for the development of organic light-emitting diodes and non-linear optical systems. In addition, depending on their substitution patterns, [2.2]paracyclophanes can display planar chirality and are nowadays considered as useful scaffolds for the development of original circularly poliarized luminescence (CPL) emitters. This perspective gives an overview on the synthesis and characterization of different families of compact luminescent compounds derived from planar chiral [2.2]paracyclophanes. The chiroptical properties of these small molecules are described, with a particular focus on their ability to emit circularly polarized luminescence in solution. Some future prospects on the design and potential applications of CPL emitters derived from pCps are finally presented. |
| Databáze: | OpenAIRE |
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