Formose reaction accelerated in aerosol-OT reverse micelles
| Autor: | Tomohiro Michitaka, Makoto Masaoka, Akihito Hashidzume |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Letter
Inorganic chemistry 010402 general chemistry Photochemistry 01 natural sciences Micelle triton X-100 formose reaction lcsh:QD241-441 chemistry.chemical_compound Aerosol OT lcsh:Organic chemistry interfacial layer aerosol-OT reverse micelles Hexadecyltrimethylammonium bromide lcsh:Science Glycolaldehyde 010405 organic chemistry water pool Organic Chemistry Carbon-13 NMR 0104 chemical sciences Formose reaction Chemistry chemistry Triton X-100 lcsh:Q Ethylene glycol hexadecyltrimethylammonium bromide |
| Zdroj: | Beilstein Journal of Organic Chemistry, Vol 12, Iss 1, Pp 2663-2667 (2016) Beilstein Journal of Organic Chemistry |
| ISSN: | 1860-5397 |
| Popis: | The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in the formose reaction. The 13C NMR spectra for the products of the formose reaction using formaldehyde-13C as starting material are indicative of the formation of ethylene glycol as a major product. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|