Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
| Autor: | Nadia Mamede José, Michel M. Brioude, Raigenis da Paz Fiuza, Luis A. S. de A. Prado, Jaime Soares Boaventura, Danilo Hansen Guimarães |
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| Jazyk: | angličtina |
| Rok vydání: | 2007 |
| Předmět: |
Condensation polymer
Materials science Bulk polymerization Ingenieurwissenschaften [620] biodiesel glycerol Dibutyltin dilaurate chemistry.chemical_compound Glycerol lcsh:TA401-492 Organic chemistry General Materials Science polyester chemistry.chemical_classification Adipic acid Chemie [540] Mechanical Engineering Polymer Condensed Matter Physics Polyester chemistry Mechanics of Materials Biodiesel production ddc:540 lcsh:Materials of engineering and construction. Mechanics of materials ddc:620 |
| Zdroj: | Materials Research, Vol 10, Iss 4, Pp 335-339 (2007) Materials Research v.10 n.4 2007 Materials research (São Carlos. Online) Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL Materials Research 4 (10): 335-339 (2007) Materials Research, Volume: 10, Issue: 4, Pages: 335-339, Published: DEC 2007 |
| ISSN: | 1516-1439 |
| Popis: | In the present work, polyesters were prepared from the polycondensation between glycerol and adipic acid using dibutyltin dilaurate as catalyst. Three glycerol: adipic acid molar ratio were used for the bulk polymerization namely: 2:2; 2:3 and 2:4. FTIR confirmed the esterification of glycerol by the acid for all the polymers. DSC and XRD indicated no crystallinity for all the polymers. The morphology of the materials are characterized by globular structure, which may suggest compositional fluctuations throughout the samples. |
| Databáze: | OpenAIRE |
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