Undecanol-ethanol-water ternary system based microextraction for the detection of cadmium
| Autor: | Şeyda Dönmez, Sabahattin Deniz, Ece Kök Yetimoğlu, Oya Aydın Urucu |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Detection limit
Cadmium Analyte Undecanol Chromatography Ternary numeral system Drop (liquid) chemistry.chemical_element heavy metal ions General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Solvent lcsh:Chemistry chemistry.chemical_compound microextraction chemistry lcsh:QD1-999 eco-friendly Phenol GFAAS |
| Zdroj: | Journal of the Serbian Chemical Society, Vol 84, Iss 4, Pp 435-443 (2019) |
| ISSN: | 1820-7421 0352-5139 |
| Popis: | An eco-friendly, simple, and sensitive solidification of floating organic drop based dispersive liquid?liquid microextraction (SFODME) procedure was introduced for the separation and preconcentration of cadmium. After 2-(5-bromo- -2-pyridylazo)-5-(diethylamino)phenol (5-Br-PADAP) was complexed with cadmium ions in sample, the undecanol?ethanol?water ternary system was used as an organic solvent for extraction. The main factors relevant to the microextraction efficiency such as pH, concentration of 5-Br-PADAP, amount of extraction solvent were optimized. The detection limit is 0.01 ?g L-1 along with preconcentration factor 266. The recovery of the analyte was between 98 % and 103 %, with relative standard deviation below 6 %. The developed procedure was successfully tested on the analysis of water, hair dye, and food samples. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|