Indium(III)‐Catalyzed Hydration and Hydroalkoxylation of α,β‐Unsaturated Ketones in Aqueous Media

Autor:	Jin-Jin Yun, Zhi-Liang Shen, Xue-Qiang Chu, Teck-Peng Loh, Man-Ling Zhi, Wen‐Xiao Shi
Přispěvatelé:	School of Physical and Mathematical Sciences
Rok vydání:	2018
Předmět:	Aqueous medium 010405 organic chemistry chemistry.chemical_element General Chemistry Hydroxylation 010402 general chemistry Indium 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Chemistry [Science] Organic chemistry Hydroalkoxylation
Zdroj:	Advanced Synthesis & Catalysis. 360:2632-2637
ISSN:	1615-4169 1615-4150
DOI:	10.1002/adsc.201800301
Popis:	The hydration of α,β-unsaturated ketones with water proceeded efficiently in the presence of In(OTf)3 (20 mol%) in aqueous media to afford synthetically versatile β-hydroxyketones in moderate to good yields with good functional group compatibility. The method also can be extended to the hydroalkoxylation of α,β-unsaturated ketones with various alcohols for the efficient synthesis of β-alkoxyketones as well as tetrahydrofuran derivatives.
Databáze:	OpenAIRE
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