Structure of [N,N'-propylenebis(2-pyrrolylmethyleneaminato)]nickel(II)
| Autor: | F. Takusagawa, K. B. Mertes, J. Sakon, A. Reiter |
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| Rok vydání: | 1989 |
| Předmět: |
chemistry.chemical_classification
Crystallography Molecular Structure Stereochemistry chemistry.chemical_element General Medicine Crystal structure General Biochemistry Genetics and Molecular Biology Planarity testing chemistry.chemical_compound Nickel chemistry Diamine Atom X-ray crystallography Organometallic Compounds Crystallization Inorganic compound Monoclinic crystal system |
| Zdroj: | Acta crystallographica. Section C, Crystal structure communications. 45 |
| ISSN: | 0108-2701 |
| Popis: | [Ni(C13H14N4)], Mr = 284.98, monoclinic, P2(1)/c, a = 10.096 (2), b = 9.360 (2), c = 30.565 (4) A, beta = 119.45 (2) degrees, V = 2515.1 (9) A3, Z = 8, Dx = 1.505 g cm-3, Cu K alpha, lambda = 1.5418 A, mu = 20.22 cm-1, F(000) = 1168, T = 298 (2) K, 437 parameters refined, final R = 0.038 for all 2587 reflections. The complex takes a square-planar geometry around the Ni atom. Although the coordination geometries of the two crystallographically independent complexes are quite similar to each other, significant differences in planarity and Ni-N distances are observed. |
| Databáze: | OpenAIRE |
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