Three dimensional excitation-emission matrix fluorescence spectroscopy of typical Japanese soil powders
| Autor: | Mihoko Moriizumi, Satoru Nakashima, Nobuyuki Naka, Yuki Nakaya, Masahiro Oguchi, Shinsuke Kashiwagi |
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| Rok vydání: | 2019 |
| Předmět: |
Soil test
Chemistry Soil organic matter Extraction (chemistry) Analytical chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence Atomic and Molecular Physics and Optics Fluorescence spectroscopy 0104 chemical sciences Analytical Chemistry Dilution Matrix (chemical analysis) Soil water 0210 nano-technology Instrumentation Spectroscopy |
| Zdroj: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 233 |
| ISSN: | 1873-3557 |
| Popis: | Front face fluorescence spectroscopy of typical Japanese soil powders (soil A: Typic Hapludand; soil H: Typic Hydraquent; soil Y: Typic Paleudult) has been conducted. Three dimensional excitation-emission matrix fluorescence spectra of the 100 wt% soils showed similar fluorescence patterns to each other. The fluorescence patterns were similar between the soil samples and their residues after extraction by NaOH solution for 60 min. In order to examine fluorescence extinction from a view point of whiteness of the soils, the soil powders were mixed with white and black diluents (Al2O3 and Fe3O4) and fluorescence spectra of the mixtures were measured at 450 nm excitation. At low levels of dilution with Al2O3 (2–100 wt% of A; 50–100 wt% of H and Y), the fluorescence intensities increased with dilution. At high levels of dilution with Al2O3, the fluorescence intensities decreased with dilution. On the other hand, fluorescent intensities decreased by dilution with Fe3O4. These results suggested inner filter effect-like fluorescence extinction by (1) large amount of blackish organic compounds giving high total carbon value and (2) blackish non-fluorescent mineral compounds. In order to correct the fluorescence intensities of the mixtures containing the sample soils and the diluents, we preliminary applied a correction method based on the Kubelka-Munk theory using diffuse reflectance. The corrected fluorescence intensities of samples with white diluents (Al2O3) were described by a simple fluorescence response model having saturation values. |
| Databáze: | OpenAIRE |
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