Schiff-base coordination complexes with plutonium(iv) and cerium(iv)
Autor: | David S. Meeker, Matthew L. Marsh, Bonnie E. Klamm, Cory J. Windorff, Thomas E. Albrecht-Schmitt |
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Rok vydání: | 2018 |
Předmět: |
Schiff base
010405 organic chemistry Near-infrared spectroscopy Metals and Alloys chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Redox Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Plutonium Cerium chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Cyclic voltammetry Single crystal Nuclear chemistry |
Zdroj: | Chemical communications (Cambridge, England). 54(62) |
ISSN: | 1364-548X |
Popis: | PuL2 and CeL2 (L = N,N'-bis[(4,4'-diethylamino)salicylidene]-1,2-phenylenediamine) have been synthesized, and characterized by single crystal X-ray diffraction, UV/vis/NIR spectroscopy, and cyclic voltammetry. These studies reveal the enhanced stabilization of Pu(iv) versus Ce(iv) with this Schiff base, and quasi-reversible redox behaviour only with the plutonium complex. |
Databáze: | OpenAIRE |
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