Synthesis and Magnetic Properties of Two-Step-Coordination Schiff Base Clusters
| Autor: | Peter C. M. Christianen, Uli Zeitler, Paul Tinnemans, J.C. Maan, Hans Engelkamp, Alan E. Rowan, Laurens Peters |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Soft Condensed Matter & Nanomaterials (HFML) Schiff base Chemistry Molecular Materials chemistry.chemical_element Crystal structure Manganese Correlated Electron Systems / High Field Magnet Laboratory (HFML) Solid State Chemistry Coordination complex Inorganic Chemistry Paramagnetism chemistry.chemical_compound Crystallography Transition metal Soft Condensed Matter and Nanomaterials Cluster (physics) Semiconductors and Nanostructures Pincer ligand |
| Zdroj: | European Journal of Inorganic Chemistry, 2021, 26, pp. 2611-2617 European Journal of Inorganic Chemistry, 2021, 2611-2617 |
| ISSN: | 1434-1948 |
| Popis: | A new family of paramagnetic coordination compounds based on a diimine-pyridine pincer ligand has been prepared, using a two-step synthetic approach. The sequential introduction of identical or different transition metals (Co, Mn, Ni, Zn) afforded mono-, di-, tri- and tetranuclear clusters, whose crystal structure has been determined. Magnetic studies reveal that the metals within the trinuclear manganese cluster engage in a small ferromagnetic exchange interaction (J=0.15 K). These studies enable the design of new clusters with specific magnetic properties. |
| Databáze: | OpenAIRE |
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