The diiodomethyl-sulfonyl moiety: an unexplored halogen bond-donor motif
| Autor: | Maurizio Ursini, Pierangelo Metrangolo, Giancarlo Terraneo, Tullio Pilati, Tatsuo Kaiho, Valentina Dichiarante, Giuseppe Resnati |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
Sulfonyl chemistry.chemical_classification Halogen bond 010405 organic chemistry Metals and Alloys Solid-state General Chemistry Crystal structure 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Halogen Materials Chemistry Ceramics and Composites Moiety |
| Zdroj: | Chemical communications (Cambridge, England). 55(29) |
| ISSN: | 1364-548X |
| Popis: | Herein, we report the crystal structures of the antimicrobial agent diiodomethyl-p-tolylsulfone and of three halogen bonded co-crystals demonstrating that the bioactive moiety -SO2CHI2 can function as a quite effective halogen bond based motif in the solid state and in solution, namely demonstrating that α-iodosulfones may become a new entry in the quite small group of alkyl-iodides functioning as reliable halogen bond-donors. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|