Recent advances in analytical figures of merit: Heteroscedasticity strikes back
| Autor: | Alejandro C. Olivieri, Franco Allegrini |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Quimiometria
Heteroscedasticity Computer science General Chemical Engineering Otras Ciencias Químicas 010401 analytical chemistry General Engineering Ciencias Químicas Estimator Multivariate calibration 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Quimica Analitica 0104 chemical sciences Analytical Chemistry Econometrics Figure of merit Sensitivity (control systems) Social science 0210 nano-technology CIENCIAS NATURALES Y EXACTAS |
| Popis: | With a growing number of analytical methodologies incorporating multivariate calibration models, the development of suitable estimators of their analytical figures of merit is playing an important role in modern analytical chemistry. The main goal of this mini-review is to briefly present the recent trends regarding reliable and interpretable estimators of traditional figures of merit such as sensitivity, prediction uncertainty and detection limit. Heteroscedasticity in instrumental measurements is driving some of these recent developments and influencing the definition of new estimators. Fil: Allegrini, Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina Fil: Olivieri, Alejandro Cesar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina |
| Databáze: | OpenAIRE |
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