Synthesis of dialkyl carbonates from CO2 and alcohols via electrogenerated N-heterocyclic carbenes

Autor:	Yan Xiao, La-Xia Wu, Huan Wang, Bin-Bin Ding, Zhuo-Ying Tu, Jia-Xing Lu
Jazyk:	angličtina
Rok vydání:	2012
Předmět:	lcsh:Chemistry chemistry.chemical_compound chemistry lcsh:Industrial electrochemistry lcsh:QD1-999 Ionic liquid Carbon fixation Electrochemistry Organic chemistry Electrosynthesis Selectivity lcsh:TP250-261
Zdroj:	Electrochemistry Communications, Vol 25, Iss, Pp 116-118 (2012)
ISSN:	1388-2481
Popis:	Here we describe the utilization of NHC–CO2 which transfers CO2 to alcohols for the synthesis of dialkyl carbonates under mild conditions with high conversion and excellent selectivity. In addition NHC–CO2 formation was supported by electrochemical analysis. This study provides a new procedure for the synthesis of dialkyl carbonates of chemical and pharmaceutical interest, as well as expands the applications of NHCs in CO2 fixation. Keywords: N-heterocyclic carbenes, Electrosynthesis, CO2, Dialkyl carbonates, Ionic liquid
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f1efafe80265a0dee3f353e17c6acab5 http://www.sciencedirect.com/science/article/pii/S1388248112004018 Zobrazit plný text záznamu Full Text from ScienceDirect