Electron-spin-resonance studies of porous polyacenic semiconductive materials

Autor: Kazuyoshi Tanaka, Masahiro Kobashi, Tokio Yamabe, Shizukuni Yata, Jun Yamauchi, Hideki Sanekata
Rok vydání: 1991
Předmět:
Zdroj: Physical Review B. 44:1101-1104
ISSN: 1095-3795
0163-1829
DOI: 10.1103/physrevb.44.1101
Popis: Electron-spin-resonance (ESR) studies of porous polyacenic semiconductive materials in the pristine and the heavily ${\mathrm{I}}_{2}$-doped regimes have been carried out. The measurement temperature has been varied from 15 K to room temperature. Two kinds of typical polyacenic semiconductive sample essentially prepared by pyrolysis at 600 \ifmmode^\circ\else\textdegree\fi{}C and 700 \ifmmode^\circ\else\textdegree\fi{}C of phenol-formaldehyde resin were selected for the ESR measurements. In particular, the temperature-dependent behavior of the peak-to-peak linewidth of the ESR line shape for all samples was discussed in detail, particularly in relation to the hopping behavior of unpaired spins.
Databáze: OpenAIRE