| Autor: |
Ewa Machalska, Grzegorz Zając, Malgorzata Baranska, Petr Bouř, Dorota Kaczorek, Robert Kawęcki, Joanna E. Rode, Krzysztof Lyczko, Jan Cz. Dobrowolski |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Chemical communications (Cambridge, England). 58(28) |
| ISSN: |
1364-548X |
| Popis: |
In this study, we found that a recently discovered ECD-Raman effect dominated over the natural Raman optical activity in a series of atropisomeric naphthalenediimides, and we investigated the kind of information about the molecular structure that could be obtained from the spectra. The ECD-Raman effect is polarised Raman scattering modulated by electronic circular dichroism. We showed that the spectra significantly depended on the substitution of the solute and/or the change of the solvent. Moreover, the spectra could be well-predicted by the theory, thus providing an interesting tool to monitor the chirality of the binaphthyl compounds. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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