REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES

Autor: Paul D. Beer, Christopher J. Jones, Jon A. McCleverty, Sithy S. Salam
Jazyk: angličtina
Rok vydání: 1987
Předmět:
Zdroj: JOURNAL OF INCLUSION PHENOMENA. 5(4)
ISSN: 1573-1111
0167-7861
Popis: A series of cyclic polyethers, which incorporate the redox active {Mo(NO)}3+ moiety, have been prepared and characterised. The electrochemistry of these complexes has been investigated and their reduction potentials found to undergo anodic shifts upon the binding of alkali metal cations to the cyclic polyether moiety. The magnitude of the shift appears relatively insensitive to the size of the cyclic polyether ring, but is substantially reduced when K+ is used in place of Na+. © 1987 D. Reidel Publishing Company.
Databáze: OpenAIRE
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