Medium-Chain Chlorinated Paraffins (CPs) Dominate in Australian Sewage Sludge
| Autor: | Jacob de Boer, Caroline Gaus, Christie Gallen, Jochen F. Mueller, Pim E.G. Leonards, Christian Bogdal, Jake W. O'Brien, Geoff Eaglesham, Sicco H. Brandsma, Louise M. van Mourik |
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| Přispěvatelé: | E&H: Environmental Bioanalytical Chemistry, AIMMS, E&H: Environmental Chemistry and Toxicology, Chemistry and Biology |
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
0211 other engineering and technologies
Sewage Atmospheric-pressure chemical ionization 02 engineering and technology 010501 environmental sciences 01 natural sciences Article Dry weight Chlorinated paraffins Journal Article Hydrocarbons Chlorinated Environmental Chemistry 0105 earth and related environmental sciences 021110 strategic defence & security studies business.industry Chemistry Australia General Chemistry 6. Clean water Paraffin Environmental chemistry Sewage treatment SDG 6 - Clean Water and Sanitation business Sludge Environmental Monitoring |
| Zdroj: | Environmental Science & Technology Environmental Science and Technology, 51(6):6, 3364-3372. American Chemical Society Brandsma, S H, van Mourik, L, O'Brien, J W, Eaglesham, G, Leonards, P E G, de Boer, J, Gallen, C, Mueller, J, Gaus, C & Bogdal, C 2017, ' Medium-Chain Chlorinated Paraffins (CPs) Dominate in Australian Sewage Sludge ', Environmental Science and Technology, vol. 51, no. 6, 6, pp. 3364-3372 . https://doi.org/10.1021/acs.est.6b05318 |
| ISSN: | 1520-5851 0013-936X |
| DOI: | 10.1021/acs.est.6b05318 |
| Popis: | To simultaneously quantify and profile the complex mixture of short-, median-, and long-chain CPs (SCCPs, MCCPs, and LCCPs) in Australian sewage sludge, we applied and further validated a recently developed novel instrumental technique, using quadrupole time-of-flight high resolution mass spectrometry running in the negative atmospheric pressure chemical ionization mode (APCI-qTOF-HRMS). Without using an analytical column the cleaned extracts were directly injected into the qTOF-HRMS followed by quantification of the CPs by a mathematical algorithm. The recoveries of the four SCCP, MCCP and LCCP-spiked sewage sludge samples ranged from 86 to 123%. This APCI-qTOF-HRMS method is a fast and promising technique for routinely measuring SCCPs, MCCPs, and LCCPs in sewage sludge. Australian sewage sludge was dominated by MCCPs with concentrations ranging from 542 to 3645 ng/g dry weight (dw). Lower SCCPs concentrations ( |
| Databáze: | OpenAIRE |
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