Vibrational modes of the stibine molecule
| Autor: | F. Michelot, N. Sanzharov, Claude Leroy, L. Pluchart, Elena Sergeevna Bekhtereva, O.N. Ulenikov |
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| Přispěvatelé: | Laboratoire de Physique de l'Université de Bourgogne (LPUB), Université de Bourgogne (UB)-Centre National de la Recherche Scientifique (CNRS), Lab Mol Spect, Dept Phys, Tomsk State University [Tomsk], Laboratoire de Physique de l'Université de Bourgogne ( LPUB ), Université de Bourgogne ( UB ) -Centre National de la Recherche Scientifique ( CNRS ) |
| Rok vydání: | 2005 |
| Předmět: |
High excited levels
[ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph] Stibine Algebraic approach Vibrational modes 01 natural sciences Molecular physics Hot band chemistry.chemical_compound [PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph] 0103 physical sciences Molecular symmetry Molecule SbH3 molecule Physics::Chemical Physics Physical and Theoretical Chemistry 010306 general physics Spectroscopy Coupling Physics Quantitative Biology::Biomolecules 010304 chemical physics Group (mathematics) Operator (physics) Atomic and Molecular Physics and Optics chemistry Molecular vibration |
| Zdroj: | Journal of Molecular Spectroscopy Journal of Molecular Spectroscopy, Elsevier, 2005, 232 (2), pp.119-136. ⟨10.1016/j.jms.2005.03.006⟩ Journal of Molecular Spectroscopy, Elsevier, 2005, 232 (2), pp.119-136. 〈10.1016/j.jms.2005.03.006〉 |
| ISSN: | 0022-2852 1096-083X |
| DOI: | 10.1016/j.jms.2005.03.006 |
| Popis: | International audience; In this paper, we use the algebraic approach to describe the vibrational modes of stibine molecule (of C3v molecular symmetry group) up to 21 quanta. As the stibine molecule exhibits stretch-bend resonances, we build an algebraic pyramidal coupling operator between stretching modes and bending modes adapted to this molecule. The standard deviation associated to the fit of the vibrational levels is 1.75 cm-1. |
| Databáze: | OpenAIRE |
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