A new protocol for nickel-catalysed regio- and stereoselective hydrocyanation of allenes
| Autor: | Hiroto Hori, Yuka Amako, Atsushi Nishida, Shigeru Arai |
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| Rok vydání: | 2015 |
| Předmět: |
Cyclopropanes
Single product Double bond Stereochemistry chemistry.chemical_element Stereoisomerism Catalysis chemistry.chemical_compound Nickel Nitriles Materials Chemistry Hydrocyanation Organic chemistry Cyanates chemistry.chemical_classification Aryl Metals and Alloys General Chemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Cyclization Alkynes Ceramics and Composites Stereoselectivity |
| Zdroj: | Chemical communications (Cambridge, England). 51(35) |
| ISSN: | 1364-548X |
| Popis: | Regio- and stereoselective hydrocyanation under nickel catalysis is described. This report shows that allenyl C–C double bonds are discriminated and converted to the corresponding carbonitriles as a single product. The key functionalities for achieving high regio- and stereocontrol are aryl and cyclopropyl groups in the substrates. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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