Transition-Metal-Free C(sp3)–H Oxidation of Diarylmethanes
| Autor: | Bi-Hui Zhou, Wenzhe Ren, Li-Mei Fan, Jie Li, Qiannan Luo, Fan Yang, Pu Chen, Dong Zou, Linlin Li |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
metal-free
Ketone oxidation Pharmaceutical Science diarylmethane 010402 general chemistry 01 natural sciences Analytical Chemistry lcsh:QD241-441 Transition metal lcsh:Organic chemistry Drug Discovery Polymer chemistry Physical and Theoretical Chemistry chemistry.chemical_classification Molecular Structure 010405 organic chemistry Chemistry Communication Organic Chemistry ketone Ketones 0104 chemical sciences Metal free Chemistry (miscellaneous) Molecular Medicine Methane Oxidation-Reduction |
| Zdroj: | Molecules, Vol 23, Iss 8, p 1922 (2018) Molecules : A Journal of Synthetic Chemistry and Natural Product Chemistry |
| ISSN: | 1420-3049 |
| Popis: | An efficient direct C(sp3)–H oxidation of diarylmethanes has been demonstrated by this study. This method employs environment-friendly O2 as an oxidant and is promoted by commercially available MN(SiMe3)2 [M = K, Na or Li], which provides a facile method for the synthesis of various diaryl ketones in excellent yields. This protocol is metal-free, mild and compatible with a number of functional groups on substrates. |
| Databáze: | OpenAIRE |
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