Green alcohol oxidation on palladium catalysts supported on amphiphilic hybrid carbon nanotubes
| Autor: | Rosa Axet, Stéphane Louisia, Anas Benyounes, Philippe Serp, Ziyad Mahfoud, Mohamed Kacimi |
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| Přispěvatelé: | Laboratoire de chimie de coordination (LCC), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie de Toulouse (ICT-FR 2599), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université Mohammed V de Rabat [Agdal], Laboratoire de Physique des Solides (LPS), Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11) |
| Rok vydání: | 2015 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Ketone chemistry.chemical_element [CHIM.CATA]Chemical Sciences/Catalysis [CHIM.MATE]Chemical Sciences/Material chemistry General Chemistry Carbon nanotube Aldehyde Catalysis law.invention chemistry.chemical_compound chemistry law Benzyl alcohol Alcohol oxidation Polymer chemistry Organic chemistry [CHIM.COOR]Chemical Sciences/Coordination chemistry Carbon nanotube supported catalyst Palladium |
| Zdroj: | Catalysis Today Catalysis Today, Elsevier, 2015, 249, pp.137-144. ⟨10.1016/j.cattod.2014.11.019⟩ |
| ISSN: | 0920-5861 |
| DOI: | 10.1016/j.cattod.2014.11.019 |
| Popis: | International audience; In this work, unique amphiphilic magnetic hybrid carbon nanotubes that contain on the same nanotube two different sections: a hydrophobic undoped part connected to a hydrophilic N-doped segment are synthesized and used as supports for palladium catalysts. These new Pd-supported catalysts have been used in the alcohol oxidation reaction using molecular oxygen in the liquid phase. The oxidation of 2-heptanol produces selectively the ketone, the oxidation of benzyl alcohol is very selective towards the aldehyde, and ethanol oxidation produces selectively acetic acid. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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