Palladium Complexes Comprising C(4)-bound Diimidazolylidene Carbenes

Autor:	Marion Heckenroth, Martin Albrecht
Jazyk:	němčina
Rok vydání:	2008
Předmět:	Olefin fiber chemistry.chemical_element Abnormal bonding General Medicine General Chemistry Catalytic alkene hydrogenation Medicinal chemistry Catalysis chemistry.chemical_compound Chemistry chemistry Reactivity (chemistry) Lewis acids and bases N-heterocyclic carbenes Carbene QD1-999 Palladium
Zdroj:	CHIMIA, Vol 62, Iss 4 (2008)
ISSN:	2673-2424 0009-4293
Popis:	Imidazolium-derived palladium dicarbene complexes have been synthesized which feature either normal C(2) carbene bonding or abnormal C(4) bonding. Comparison of the reactivity of these complexes, in particular towards Lewis acids (H+, Ag+), indicate consistently that C(4)-bound carbenes are stronger donors than their C(2)-bound analogs. As a consequence of this electronic impact, palladium complexes comprising C(4)-bound dicarbene ligands were found to be efficient catalysts for olefin hydrogenation under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f01edafc1f00888ecb494e1c917d5c9e https://chimia.ch/chimia/article/view/4473 Zobrazit plný text záznamu