Structure of Copper(II) Complexes with 2-[2-Hydroxy-Phenil]-4,4-Diphenyl-1,2-Dihydro-4H-3,1-Benzoxazine in Chloroform

Autor: S. N. Bolotin, N. N. Bukov, M. H. Shamsutdinova, E. L. Isaeva, K. S. Pushkareva
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Advances in Physical Chemistry, Vol 2009 (2009)
ISSN: 1687-7985
DOI: 10.1155/2009/365949
Popis: Electronic spectra of copper(II) complexes C u L 2 and C u 2 L 2 A c 2 (L-2-[2-hydroxy-phenil]-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine, Ac – C H 3 C O O − ) (L) in chloroform are studied. It is shown that complex C u l 2 has rhombic bipyramid polyhedron and complex C u 2 L 2 A c 2 has tetragonal pyramidal polyhedron of copper ion. Results of definition of geometry for complexes in solution correlate with structure of solid complexes.
Databáze: OpenAIRE