Enantioselective Iron-Catalyzed Intramolecular Cyclopropanation Reactions

Autor:	Shou-Fei Zhu, Qi-Lin Zhou, Xiu-Lan Xie, Huan Xu, Jun-Jie Shen, Yan Cai
Rok vydání:	2014
Předmět:	inorganic chemicals Chemistry Cyclopropanation organic chemicals Iron catalyzed Enantioselective synthesis General Medicine General Chemistry Medicinal chemistry Catalysis Metal visual_art Intramolecular force visual_art.visual_art_medium Organic chemistry heterocyclic compounds Carbenoid
Zdroj:	Angewandte Chemie International Edition. 53:13188-13191
ISSN:	1433-7851
DOI:	10.1002/anie.201406853
Popis:	An iron-catalyzed asymmetric intramolecular cyclopropanation was realized in high yields and excellent enantioselectivity (up to 97 % ee) by using the iron complexes of chiral spiro-bisoxazoline ligands as catalysts. The superiority of iron catalysts exhibited in this reaction demonstrated the potential abilities of this sustainable metal in asymmetric carbenoid transformation reactions.
Databáze:	OpenAIRE
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