Crystal Structure, Topological and Hirshfeld Surface Analysis of a Zn(II) Zwitterionic Schiff Base Complex Exhibiting Nonlinear Optical (NLO) Properties Using Z-Scan Technique
| Autor: | Abdullah Alarifi, Mohd Muslim, Mohd Mehkoom, Mohd. Muddassir, Musheer Ahmad, Ahmad Alowais, Mohd Afzal, Saima Kamaal, Syed Mohammad Afzal, Awad Naseer Albalwi |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Materials science
General Chemical Engineering Dimer zwitterion 02 engineering and technology Crystal structure Zn(II) complex single crystal XRD 010402 general chemistry Topology 01 natural sciences Inorganic Chemistry Crystal chemistry.chemical_compound Ultraviolet visible spectroscopy Hirshfeld surface analysis General Materials Science Z-scan technique Schiff base Crystallography 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences third-order NLO Trigonal bipyramidal molecular geometry chemistry QD901-999 0210 nano-technology Single crystal |
| Zdroj: | Crystals Volume 11 Issue 5 Crystals, Vol 11, Iss 508, p 508 (2021) |
| ISSN: | 2073-4352 |
| DOI: | 10.3390/cryst11050508 |
| Popis: | A mononuclear Zn(II) complex of (Zn(H2L) (CH3OH) Cl2) (1) has been synthesized by using a nonlinear optically active Zwitterionic Schiff base which is 4-((2-hydroxy-3-methoxybenzylidene) amino) benzoic acid (H2L). Complex 1 has been structurally analyzed by FTIR and UV spectroscopy, TGA, Powder-XRD and single crystal X-ray diffraction. X-Ray crystallographic studies revealed Zn(II) complex crystallizes in a P21/c space group and exists in a distorted trigonal bipyramidal geometry (τ = 0.68). The topological analysis of complex 1 showed that the underlying net is characterized by an unknown topological type and point symbol {342.468.510}, and multilevel analysis of complex packing as dimer gives a 18-c uninodal net with unknown topological type and point symbol {348.499.56}. The calculation results of a Hirshfeld surface analysis have been investigated to explore the H-bonding within the crystal. Third-order non-linear properties were also studied, which revealed that the lower input power (5.0 mM) for the material shows full transparency however, it becomes opaque for higher input power. Such limiting behavior of complex 1 suggests its potential for instrumental protective devices against high laser illuminations. |
| Databáze: | OpenAIRE |
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