Total Synthesis of Viridiofungin A

Autor:	Kenji Morokuma, Jun Ishihara, Keisuke Takahashi, Susumi Hatakeyama
Rok vydání:	2005
Předmět:	Stereochemistry Metathesis Catalysis chemistry.chemical_compound Bromide Materials Chemistry Organometallic Compounds Organic chemistry Citrates Alkyl Trichoderma chemistry.chemical_classification Molecular Structure biology Alkene Trichoderma viride Metals and Alloys Total synthesis Stereoisomerism General Chemistry General Medicine Ketones biology.organism_classification Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Ceramics and Composites Tyrosine Stereoselectivity Citric acid
Zdroj:	ChemInform. 36
ISSN:	1522-2667 0931-7597
Popis:	Viridiofungin A, a member of amino alkyl citrate antibiotics from Trichoderma viride, was enantioselectively synthesized in naturally occurring form for the first time, employing regio- and stereoselective opening of the chiral glycidate with vinylmagnesium bromide and alkene cross metathesis of the citric acid core and hexadec-15-en-8-one as key steps.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::efd41ec725382b8842ba3ec6bf83264b https://doi.org/10.1002/chin.200538212 Zobrazit plný text záznamu Plný text