Electrospray mass spectrometry (ESI-MS) in the study of metal–ligand solution equilibria
| Autor: | G. Giorgio Bombi, Valerio Di Marco |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Electrospray
Electrospray mass spectrometry Metal ions in aqueous solution Electrospray ionization Analytical chemistry Mass spectrometry ESI-MS solution chemistry metal–ligand complexation solution equilibria General Biochemistry Genetics and Molecular Biology Analytical Chemistry Inclusion compound Metal chemistry.chemical_compound Computational chemistry Spectroscopy Chemistry Ligand General Medicine Condensed Matter Physics Stability constants of complexes visual_art visual_art.visual_art_medium Stoichiometry |
| Zdroj: | Mass Spectrometry Reviews. 25:347-379 |
| ISSN: | 1098-2787 0277-7037 |
| DOI: | 10.1002/mas.20070 |
| Popis: | In the 20 years, since the introduction of electrospray mass spectrometry (ESI-MS), the use of this technique in various fields of inorganic, organometallic, and analytical chemistry has been steadily increasing. In this study, the application of ESI-MS to the study of metal–ligand solution equilibria is reviewed (till 2004 included). In a first section, advantages and drawbacks of ESI-MS in this type of application are described. Subsequently, a list of ca. 300 studies is reported, in which ESI-MS was used to give number and stoichiometry of the species at equilibrium, or also to estimate their stability constants. All studies are classified according to the metal ions under examination. Other related applications, such as host–guest interactions and metal ion-protein binding studies, are briefly reviewed as well. © 2005 Wiley Periodicals, Inc., Mass Spec Rev 25:347–379, 2006 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text