Room-Temperature-Observable Interconversion Between Si(IV) and Si(II) via Reversible Intramolecular Insertion Into an Aromatic C-C Bond

Autor:	Teresa Eisner, Arseni Kostenko, Franziska Hanusch, Shigeyoshi Inoue
Rok vydání:	2021
Předmět:	Isomerism Research Article Research Articles equilibrium Si ligands silylene silepins small molecule activation Organic Chemistry Temperature Thermodynamics General Chemistry Catalysis Density Functional Theory ddc
Popis:	An easily isolable silacycloheptatriene (silepin) 1 b was synthesized from the reaction of a N-heterocyclic imino (IPrN) substituted tribromosilane IPrNSiBr
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eed5bbe8ce7fe7ab1d806442c4cb6ad7 https://mediatum.ub.tum.de/1707505 Zobrazit plný text záznamu