Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants
| Autor: | Damien Montarnal, Rinish Reddy Vaidyula, Elodie Bourgeat-Lami, Pierre-Yves Dugas, Eleanor Rawstron |
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| Přispěvatelé: | Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265 (C2P2), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École supérieure de Chimie Physique Electronique de Lyon (CPE)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Base (chemistry) Carboxylic acid education Organic Chemistry Bioengineering 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry 0104 chemical sciences Miniemulsion Hydrolysis chemistry.chemical_compound [CHIM.POLY]Chemical Sciences/Polymers Vitrimers chemistry Polymerization Chemical engineering Reagent Carboxylate 0210 nano-technology |
| Zdroj: | Polymer Chemistry Polymer Chemistry, Royal Society of Chemistry-RSC, 2019, 10 (23), pp.3001-3005. ⟨10.1039/C9PY00644C⟩ |
| ISSN: | 1759-9962 1759-9954 |
| Popis: | International audience; Epoxy-acid vitrimer particles with excellent osmotic and hydrolytic stability were synthesized by miniemulsion polymerization thanks to in situ generation of surfactants from the carboxylic acid reagent and a water-soluble base. The sulfate-free vitrimers formed in this way show greatly reduced creep viscosities. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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