Synergistic Effects of Earth-Abundant Metal–Metal Oxide Enable Reductive Amination of Carbonyls at 50 °C
| Autor: | Hitoshi Abe, Michikazu Hara, Yasuhiro Niwa, Debraj Chandra, Manas Kumar Bhunia |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | ACS Applied Materials & Interfaces. 14:4144-4154 |
| ISSN: | 1944-8252 1944-8244 |
| Popis: | Reductive amination of carbonyls to primary amines is of importance to the synthesis of fine chemicals; however, this reaction with heterogeneous catalysts containing earth-abundant metals under mild conditions remains scarce. Here, we show that the nickel catalyst with mixed oxidation states enables such synthesis of primary amines under low temperature (50 °C) and H |
| Databáze: | OpenAIRE |
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