Synergism of thiocyanate ions and microinterfacial surface as driving forces for heavy multi-metals extraction
| Autor: | Adina Roxana Petcu, Maria Mihaly, Nicoleta Liliana Olteanu, Elena Adina Andrei, Aurelia Meghea, Cosmina Andreea Marin, Daniela Cadar |
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| Rok vydání: | 2018 |
| Předmět: |
Aqueous solution
Thiocyanate General Chemical Engineering Inorganic chemistry Extraction (chemistry) Aqueous two-phase system chemistry.chemical_element 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology 010403 inorganic & nuclear chemistry 01 natural sciences 0104 chemical sciences lcsh:Chemistry chemistry.chemical_compound Chromium Nickel lcsh:QD1-999 chemistry Microemulsion 0210 nano-technology Butyl acetate |
| Zdroj: | Arabian Journal of Chemistry, Vol 11, Iss 4, Pp 501-512 (2018) |
| ISSN: | 1878-5352 |
| DOI: | 10.1016/j.arabjc.2017.11.018 |
| Popis: | A comprehensive study has been carried out to evaluate the extraction of heavy metals mixture (Co2+, Cr3+, Cu2+, Ni2+) from aqueous media by Winsor II non-ionic microemulsion, containing polyoxyethylene (4) lauryl ether as non-ionic surfactant and butyl acetate as organic phase. The extraction mechanism is based on the formation of thiocyanate complexes of metals and their transfer from aqueous to microemulsion phase, either towards the interfacial film of surfactant (Co2+) or into the core of micelles (Cr3+, Cu2+, Ni2+). The value of the distribution coefficient for Co2+ was higher than for the other studied metals and its extraction efficiency was not dependent on the working conditions, showing a maximum value (99.99%) in all cases. By using successive extractions, chromium, nickel and copper ions that remained in the aqueous phase after first extraction were transported into the microemulsion phase, leading to an increase in the extraction efficiency up to 99.99% for chromium and copper, and 85% for nickel. Based on pH influence, a selective extraction of Co2+ and Cr3+ can be achieved, since the cobalt ions were completely extracted into the microemulsion phase at pH = 1, and the chromium ions still remained in the aqueous phase. Keywords: Nonionic microemulsion, Thiocyanate complexes of heavy metals, Simultaneous heavy metals extraction, Microinterfacial effect, Synergism |
| Databáze: | OpenAIRE |
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