Visible-Light-Mediated Catalytic Hydroacylation of Dialkyl Azodicarboxylates by Graphite Flakes
| Autor: | Christoforos G. Kokotos, Giorgos Koutoulogenis, Dimitris Limnios, Errika Voutyritsa, Maroula G. Kokotou |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Hydroacylation Substrate (chemistry) chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Catalysis chemistry Organic chemistry Graphite Physical and Theoretical Chemistry Efficient catalyst Carbon Visible spectrum |
| Zdroj: | Organic Letters. 19:1760-1763 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/acs.orglett.7b00519 |
| Popis: | A novel and efficient metal-free catalyzed hydroacylation of dialkyl azodicarboxylates is reported. Graphite flakes were found to be the most efficient catalyst among other carbon-based materials to promote this reaction. This unprecedented catalytic activity can be expanded into a wide substrate scope of aliphatic aldehydes bearing various functional groups, leading to the corresponding products in good to excellent yields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|