Amorphous Framework in Electrodeposited CuBiTe Thermoelectric Thin Films with High Room-Temperature Performance
Autor: | N. Padmanathan, Swatchith Lal, Kafil M. Razeeb, Devendraprakash Gautam |
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Rok vydání: | 2021 |
Předmět: |
Materials science
business.industry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Thermoelectric materials 01 natural sciences 7. Clean energy Ternary alloy 0104 chemical sciences Electronic Optical and Magnetic Materials Amorphous solid chemistry.chemical_compound chemistry Thermoelectric effect Materials Chemistry Electrochemistry Optoelectronics Bismuth telluride Thin film 0210 nano-technology Electroplating business |
Zdroj: | ACS applied electronic materials. 3(4) |
ISSN: | 2637-6113 |
Popis: | Bismuth telluride-based alloys are the most efficient thermoelectric materials near room temperature and widely used in commercial thermoelectric devices. Nevertheless, their thermoelectric performance needs to be improved further for wide-scale implementation either as a thermoelectric generator or cooler. Here, we propose a simultaneous codeposition of CuBiTe thin films and their phase transition strategy via the traditional electrodeposition process. With just 13 atom % Cu doping, crystalline-to-amorphous phase transformation resulted for the electroplated CuBiTe alloy. A close look at the alloy composition revealed spike-shaped nanocrystalline Bi |
Databáze: | OpenAIRE |
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