Electric-field-induced IR absorption in diamond

Autor: F. N. Onyango
Rok vydání: 1976
Předmět:
Zdroj: Journal of Physics C: Solid State Physics. 9:L533-L536
ISSN: 0022-3719
DOI: 10.1088/0022-3719/9/19/004
Popis: Electric-field-induced absorption of a type IIa diamond has been measured at various resolutions over a wider spectral range (2300 to 2700 cm-1) than hitherto. A new feature has been observed at 2335 cm-1 close to the Raman-active but otherwise infrared-inactive band at 2339 cm-1. Higher-resolution (5 cm-1) measurements in the neighbourhood of the k approximately=0 overtone resulted in a band being observed at exactly twice the Raman frequency, namely 2664 cm-1. This frequency is compared with a previous field-induced infrared result at 2660 cm-1 measured at a resolution of 28 cm-1 and a Raman scattering result at 2667 cm-1 measured at a resolution of 8 cm-1. The anisotropy of the overtone band is also found to agree with theoretical predictions.
Databáze: OpenAIRE