Photocatalytic degradation of industrial dye using hybrid filler impregnated poly-sulfone membrane and optimizing the catalytic performance using Box-Behnken design

Autor: Sadaf Ul Hassan, Sidra Shafique, Bushra Anees Palvasha, Muhammad Haris Saeed, Syed Ali Raza Naqvi, Sohail Nadeem, Syed Irfan, Toheed Akhter, Asim Laeeq Khan, Muhammad Shahid Nazir, Murid Hussain, Young-Kwon Park
Rok vydání: 2023
Předmět:
Zdroj: Chemosphere. 313:137418
ISSN: 0045-6535
DOI: 10.1016/j.chemosphere.2022.137418
Popis: Mixed Matrix Membranes have gained significant attention over the past few years due to their diverse applications, unique hybrid inorganic filler and polymeric properties. In this article, the impregnation of nano-hybrid filler (polyoxometalates (∼POMs) encapsulated into the metal-organic framework (MOF) ∼ PMOF) on the polysulfone membrane (∼PSF) was done, resulting in a mix matrix membrane (∼PMOF@PSF). The developed structure was characterized by Fourier transform infrared (FT-IR), powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and transmission electron microscopes (TEM). The results confirmed that the nano-hybrid filler was successfully fabricated on the surface of PSF. Different loading ratios of nano-hybrid filler (5%, 10%, 20%, 30%, and 40%) were used for impregnation. The study's objective was to enhance catalytic performance using optimization curves designed using a three-level Box-Behnken Design (BBD) simulation. The photodegradation of Methylene Blue (∼MB) was studied against PMOF@PSF
Databáze: OpenAIRE
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