[3+2] click chemistry approach to tetrazine containing polymers
| Autor: | David E. Chavez, Bryce C. Tappan, Valerie A. Kuehl, Andrew M. Schmalzer, Philip W. Leonard, Ruilian Wu, Greg H. Imler, Damon A. Parrish |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | RSC Advances. 12:28490-28493 |
| ISSN: | 2046-2069 |
| Popis: | We report a [3+2] cycloaddition using 3,6-bis-propargyloxy-1,2,4,5-tetrazine and azides to synthesize energetic polymers containing 1,2,4,5-tetrazine within the scaffold. This work also includes [3+2] cycloaddition to crosslink azide containing glycidyl azide polymer (GAP). These reactions provide pathways for incorporation of 1,2,4,5-tetrazine into novel energetic materials using click-chemistry and provide an alternative polymer curing approach. |
| Databáze: | OpenAIRE |
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