Study and modular synthesis of unsymmetrical bis(phosphino)pyrrole ligands

Autor:	Miles W. Johnson, Nathan D. Schley, Julia F Vidlak, Isaiah D Duplessis, Hilary D Fokwa, Sophie C Weinberg
Rok vydání:	2020
Předmět:	Inorganic Chemistry chemistry.chemical_classification Steric effects chemistry.chemical_compound chemistry Ligand Benzene Medicinal chemistry Coordination complex Pyrrole
Zdroj:	Dalton Transactions. 49:9957-9960
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt02063j
Popis:	We report the facile and modular synthesis of unsymmetrical 1,2-bis(phosphino)pyrrole ligands and their coordination chemistry. These ligands offer a promising alternative to their 1,2-bis(phosphino)benzene congeners, retaining a similar steric profile with attenuated electron donation. Proof-of-principle application of a bis(phosphino)pyrrole ligand in a nickel-catalyzed C-N cross-coupling reaction under mild conditions is demonstrated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ed856862b2d23ddbcc6bbb9fdc209901 https://doi.org/10.1039/d0dt02063j Zobrazit plný text záznamu