Bis[1-(p-chlorophenyl)-5-isopropylbiguanide-κ2N2,N4]nickel(II) dichloride dimethylformamide solvate

Autor:	F. Bentefrit, Georges Morgant, D. Nguyen-Huy, Pascale Lemoine, B. Viossat
Rok vydání:	2003
Předmět:	Hydrogen bond Stereochemistry chemistry.chemical_element General Medicine Crystal structure Medicinal chemistry General Biochemistry Genetics and Molecular Biology Crystal chemistry.chemical_compound Nickel Monomer chemistry Atom Molecule Dimethylformamide
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 59:m331-m333
ISSN:	0108-2701
DOI:	10.1107/s0108270103013519
Popis:	The asymmetric unit of the title compound, [Ni(C(11)H(16)ClN(5))(2)]Cl(2).C(3)H(7)NO, contains one monomeric nickel(II) complex cation, two Cl(-) anions and one dimethylformamide solvent molecule. The Ni atom is coordinated to each of two 1-(p-chlorophenyl)-5-isopropylbiguanide (proguanil) ligands via two N atoms. The complex exhibits a square-planar coordination, with the Ni atom lying 0.021 (2) A out of the basal plane. The crystal packing is characterized by several hydrogen bonds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ed227acd38fc353646f0655be866e979 https://doi.org/10.1107/s0108270103013519 Zobrazit plný text záznamu Plný text