NHC-alcohol adduct-mediated photocatalytic deoxygenation for the synthesis of 6-phenanthridine derivatives

Autor: Xueji Ma, Qingyun Wang, Jinge Wu, Liyuan Zhang, Aili Sun, Zhanyong Wang
Rok vydání: 2022
Předmět:
Zdroj: Organicbiomolecular chemistry. 20(27)
ISSN: 1477-0539
Popis: NHC-alcohol adduct-mediated deoxygenation of alcohols under photocatalytic conditions is described. This process provides various alkyl radicals, which can react with 2-isocyanobiaryls to afford 6-substituted phenanthridine derivatives in moderate to good yields. This method offered the first example of directly using alcohols as radical sources for 6-phenanthridine synthesis.
Databáze: OpenAIRE