A phosphine-stabilized silylene rhodium complex

Autor:	María A. Garralda, N. Almenara, Antonio Rodríguez-Diéguez, Miguel A. Huertos, J I Miranda
Rok vydání:	2019
Předmět:	Hydrogen 010405 organic chemistry Hydrosilylation Cationic polymerization Silylene chemistry.chemical_element 010402 general chemistry 01 natural sciences Carbonyl group 0104 chemical sciences Rhodium Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Benzophenone Phosphine
Zdroj:	Dalton Transactions. 48:17179-17183
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c9dt04071d
Popis:	The first phosphine-stabilized cationic rhodium silylene complex is reported. A dihydrido-silylene-Rh(iii) compound reacts with water and alcohols forming alkoxysilyl-Rh(iii) complexes and hydrogen gas. Moreover, benzophenone reacts with a cationic silylene rhodium complex leading to the reduction of the carbonyl group and the formation of an alkoxysilyl-Rh(iii) compound which has been identified as a likely intermediate in the mechanism for the hydrosilylation of ketones proposed by Hofmann and Gade.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ec66bd7b94d375a852e36ddc1d9a8220 https://doi.org/10.1039/c9dt04071d Zobrazit plný text záznamu