Anomalous charge transport in CeB6

Autor: M.I. Ignatov, V. V. Glushkov, N. Yu. Shitsevalova, A. V. Bogach, Sergey Demishev, Yu. B. Paderno, N. E. Sluchanko, A. V. Levchenko
Rok vydání: 2006
Předmět:
Zdroj: Journal of Solid State Chemistry. 179:2805-2808
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2006.01.016
Popis: The comprehensive study of conductivity σ , Hall coefficient R H and Seebeck coefficient S has been carried out on high-quality single crystals of CeB 6 in a wide range of temperatures 1.8–300 K. An anomalous behavior of all transport characteristics ( σ , R H , S ) was found for the first time in the vicinity of T * ≈80 K. The strong decrease of conductivity σ as well as the unusual asymptotic behavior of Seebeck coefficient S ( T )∼−ln T observed below T * allowed us to conclude in favor of crossover between different regimes of charge transport in CeB 6 . The pronounced change of Hall mobility μ H , which diminishes from the maximum value of 20 cm 2 /(V s) at T * to the values of ∼6 cm 2 /(V s) at T ∼10 K, seems to be attributed to the strong enhancement of charge carriers scattering due to fast spin fluctuations on Ce-sites. The low-temperature anomalies of the charge transport characteristics are compared with the predictions of the Kondo-lattice model.
Databáze: OpenAIRE