A sensing platform based on zinc-porphyrin derinative in hexadecyl trimethyl ammonium bromide (CTAB) microemulsion for highly sensitive detection of theophylline

Autor: Baojuan Zhao, Yuancui Li, Yunhan Zhao, Yan Ma, Fengjuan Li, Hongli Han, Na Wang, Xiang Wang
Rok vydání: 2022
Předmět:
Zdroj: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 281
ISSN: 1873-3557
Popis: A new porphyrin-based sensing platform in hexadecyl trimethyl ammonium bromide (CTAB) microemulsion is developed for highly sensitive detection of theophylline. In this sensing system, the zinc-porphyrin-cinnamic acid conjugate (Zn-TPPCA) works as fluorescence probe while theophylline can decrease fluorescence intensity of the probe. Further studies indicate the linear relationship between the fluorescence quenching value and the concentration of theophylline within a given range. And the introduction of CTAB microemulsion can greatly enhance sensibility and stability of this detecting system and facilitate the detection of theophylline. On the basis above, a highly sensitive sensing platform for theophylline is created with a low limit of detection (LOD) of 0.0083 μg mL
Databáze: OpenAIRE