Two Isostructural Titanium Metal-Organic Frameworks for Light Hydrocarbon Separation

Autor:	Yuexin Sun, Mei-Yan Gao, Jian Zhang, Fei Wang, Yayong Sun, Dong-Fei Lu
Rok vydání:	2021
Předmět:	chemistry.chemical_classification chemistry.chemical_element Titanium metal Methane Inorganic Chemistry chemistry.chemical_compound Adsorption Hydrocarbon chemistry Chemical engineering Cluster (physics) Physical and Theoretical Chemistry Isostructural Porosity Titanium
Zdroj:	Inorganic chemistry. 60(18)
ISSN:	1520-510X
Popis:	Presented here is the light hydrocarbon separation of titanium metal-organic frameworks (Ti-MOFs). Compared with the cyclic Ti-oxo cluster (Ti8O8(CO2)16, Ti8Ph), porous structures of FIR-125 and FIR-126 (FIR = Fujian Institute Research) can effectively improve the adsorption amounts of light hydrocarbons. The introduction of different functional groups and Ti-oxo clusters with small window sizes enables them to exhibit the highly selective separation of C2 and C3 hydrocarbons versus methane in an ambient atmosphere. The results show that Ti-MOFs are potential porous adsorbents for the separation of light hydrocarbons.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eb4d4b877fae529e592d1f472dd9d8b8 https://pubmed.ncbi.nlm.nih.gov/34498867 Zobrazit plný text záznamu