Recent Progress in the Selective Functionalization of P(O)–OH Bonds
| Autor: | Peng Cheng Qian, Biquan Xiong, Shipan Xu, Ke Wen Tang, Wai Yeung Wong, Yu Liu |
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| Rok vydání: | 2021 |
| Předmět: |
Esterification
Chemistry Phosphorus chemistry.chemical_element Organic phosphorus General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Tautomer Catalysis 0104 chemical sciences Organic molecules Small Molecule Libraries Transition metal Cyclization Metals Reagent Transition Elements Surface modification |
| Zdroj: | Topics in Current Chemistry. 379 |
| ISSN: | 2364-8961 2365-0869 |
| DOI: | 10.1007/s41061-020-00319-1 |
| Popis: | As we all know, organic phosphorus compounds have high application values in chemical industries. Compared with traditional compounds with P-X (X = Cl, Br, I) and P-H bonds, phosphorylation reagents containing P(O)-OH bonds are stable, environmentally friendly, and inexpensive. However, in recent years, there have been few studies on the selective functionalization of P(O)-OH bonds for the fabrication of P-C and P-Z bonds. In general, four-coordinated P(O)-OH compounds have reached coordination saturation due to the phosphorus atom center, but cannot evolve the phosphorus coordination center through intra-molecular tautomerization; however, the weak coordination effects between the P=O bond and transition metals can be utilized to activate P(O)-OH bonds. This review highlights the most important recent contributions toward the selective functionalization of P(O)-OH bonds via cyclization/cross coupling/esterification reactions using transition metals or small organic molecules as the catalyst. |
| Databáze: | OpenAIRE |
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