| Autor: |
Di Zhu, Ilia Korobkov, Sandro Gambarotta, Peter H. M. Budzelaar, Indira Thapa |
| Přispěvatelé: |
Zhu, Di, Thapa, Indira, Korobkov, Ilia, Gambarotta, Sandro, Budzelaar, Petrus Henricus Maria |
| Rok vydání: |
2011 |
| Předmět: |
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| Zdroj: |
Inorganic chemistry. 50(20) |
| ISSN: |
1520-510X |
| Popis: |
Knowledge about bonding in diiminepyridine (L) halide, alkyl, and dinitrogen complexes of the metals iron, cobalt, and nickel is summarized, and two new examples are added to the set: L(1)Ni(Me) and L(1)Ni(N(2)). Reactivity of these types of complexes is discussed in terms of organic radical chemistry. New C-C couplings with L(2)CoAr complexes are described and proposed to involve halide abstraction and radical coupling. Calculations support the high tendency of the diiminepyridine ligand to accept an electron coming from a metal-carbon bond and so facilitate loss of a radical. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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