Bicyclic N-Heterocyclic Carbene (Nhc) Ligand Precursors And Their Palladium Complexes
| Autor: | Bekir Çetinkaya, Namık Özdemir, M. Emin Günay, Rukiye Gümüşada |
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| Přispěvatelé: | Ondokuz Mayıs Üniversitesi |
| Rok vydání: | 2016 |
| Předmět: |
Bicyclic molecule
010405 organic chemistry Ligand camphoric acid chemistry.chemical_element 010402 general chemistry PEPPSI-type palladium complex 01 natural sciences 0104 chemical sciences PEPPSI X-ray diffraction chemistry.chemical_compound chemistry Pyridine X-ray crystallography Polymer chemistry Chiral bicyclic N-heterocyclic carbene Materials Chemistry Organic chemistry expanded ring N-heterocyclic carbene Camphoric acid Physical and Theoretical Chemistry Carbene Palladium |
| Popis: | Ozdemir, Namik/0000-0003-3371-9874; Cetinkaya, Bekir/0000-0002-4551-8650 WOS: 000377764800005 Eight bicyclic amidinium precursors (3), prepared from R,S-tmcp (R,S-tmcp: (1R,3S)-diamino-1,2,2-trimethylcyclopentane) were described. Only five of the precursors (3a-e) could be converted to palladium complexes, (PdX2(6,7-NHC)PEPPSI) (4) by treatment with PdCl2, K2CO3, and pyridine (additional KBr was used for (PdBr2(6,7-NHC)PEPPSI)). The salts and complexes were fully characterized by spectroscopic methods and X-ray crystallography. [GRAPHICS] . Scientific and Technological Research Council of Turkey [TUBITAK]Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [110T765]; Scientific Research Project Unit (BAP) of Adnan Menderes UniversityAdnan Menderes University [FEF-11019]; Scientific Research Project Unit of Ondokuz Mayis UniversityOndokuz Mayis University [F-279] This work was supported by the The Scientific and Technological Research Council of Turkey [TUBITAK, grant number 110T765]; Scientific Research Project Unit (BAP) of Adnan Menderes University [grant number FEF-11019]; Scientific Research Project Unit of Ondokuz Mayis University [grant number F-279]. |
| Databáze: | OpenAIRE |
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