The Magnetic and Magnetocaloric Properties of Pr1−x Bi x MnO3 (x = 0.2 and 0.4) Manganites

Autor: K. Sbissi, M. Ellouze, M. L. Kahn, F. Elhalouani, E.K. Hlil
Přispěvatelé: Université de Sfax - University of Sfax, Laboratoire de chimie de coordination (LCC), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie de Toulouse (ICT-FR 2599), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Magnétisme et Supraconductivité (MagSup), Institut Néel (NEEL), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Journal of Superconductivity and Novel Magnetism
Journal of Superconductivity and Novel Magnetism, Springer Verlag, 2015, 28 (5), pp.1433-1438. ⟨10.1007/s10948-015-2985-x⟩
ISSN: 1557-1939
1557-1947
Popis: The magnetic and magnetocaloric properties of Pr1−x Bi x MnO3 (x = 0.2 and 0.4) nanocrystalline manganites have been studied systematically. Samples were prepared using the Pechini sol–gel method. The variation of the magnetization as a function of temperature and applied magnetic field were carried out. Magnetic measurements show that all the materials exhibit a paramagnetic–ferromagnetic transition when the temperature decreases. Magnetocaloric effect has been calculated in terms of isothermal magnetic entropy change. A large magnetocaloric effect has been observed, the maximum entropy change, ${\Delta S}_{\mathrm {M}}^{\text {max}}$ ¦reaches 0.7 and 2.1 J kg−1 K−1 under a magnetic applied field of 5 T with an RCP values of 183 J kg−1 for Pr0.8Bi0.2MnO3 sample. These perovskites have the large magnetic entropy changes induced by low magnetic field change, which is beneficial for the household application of active magnetic refrigerant (AMR) materials.
Databáze: OpenAIRE