Isobaric vapor–liquid–liquid–solid equilibrium of the water + NaCl + 1-butanol system at 101.3 kPa
| Autor: | Vicente Gomis, Alicia Font, Jorge Garcia-Cano, Juan Carlos Asensi, María Dolores Saquete |
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| Přispěvatelé: | Universidad de Alicante. Departamento de Ingeniería Química, Universidad de Alicante. Instituto Universitario de Ingeniería de los Procesos Químicos, Equilibrio entre Fases |
| Rok vydání: | 2016 |
| Předmět: |
Isobaric
Butanol Analytical chemistry Equilibrium data Thermodynamics Water 02 engineering and technology Liquid solid 010402 general chemistry 01 natural sciences Atomic and Molecular Physics and Optics Vapor–liquid–liquid–solid 0104 chemical sciences Ingeniería Química chemistry.chemical_compound 1-Butanol 020401 chemical engineering chemistry NaCl Isobaric process General Materials Science Vapor liquid 0204 chemical engineering Physical and Theoretical Chemistry |
| Zdroj: | RUA. Repositorio Institucional de la Universidad de Alicante Universidad de Alicante (UA) |
| Popis: | A mixture of water + NaCl + 1-butanol at 101.3 kPa is studied in order to determine the influence of salt on its experimental vapor–liquid–liquid–solid equilibrium. A detailed analysis of the evolution with temperature of the different equilibrium regions is carried out. The study is conducted at a constant pressure of 101.3 kPa in a recirculating still that has been modified by our research group. The changes in the 1-butanol/water composition ratio in the vapor phase that are provoked by the salt are studied as a function of equilibrium region. In addition, the mutual solubility of 1-butanol and water is assessed in the liquid–liquid and solid–liquid regions. The authors thank the DGICYT of Spain for the financial support of project CTQ2009-13770 and CTQ2014-59496. |
| Databáze: | OpenAIRE |
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