Thermodynamic Evaluation of the Intermediate Liquid Compounds (ILC) from Biomass Fast Pyrolysis
| Autor: | Jean‐jacques Letourneau, Marion Carrier, Yi Wang, Yani Zhang, Guiyu Xiao |
|---|---|
| Přispěvatelé: | Huazhong University of Science and Technology [Wuhan] (HUST), Centre de recherche d'Albi en génie des procédés des solides divisés, de l'énergie et de l'environnement (RAPSODEE), Centre National de la Recherche Scientifique (CNRS)-IMT École nationale supérieure des Mines d'Albi-Carmaux (IMT Mines Albi), Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT), ANR: MOPGA,ANR-18-MPGA-0013, ANR-18-MPGA-0013,PYROKINE,Pyrolyse rapide de la biomasse des déchets: double cinétique(2018) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Activity coefficient
Equation of state Materials science Atmospheric pressure 020209 energy Hydroxyacetone Thermodynamics Flash evaporation 02 engineering and technology Fast Pyrolysis Pyrolyse rapide 7. Clean energy chemistry.chemical_compound 020401 chemical engineering chemistry 13. Climate action [CHIM.ANAL]Chemical Sciences/Analytical chemistry Biomasse 0202 electrical engineering electronic engineering information engineering [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering Methanol Biomass 0204 chemical engineering Pyrolysis UNIFAC |
| Zdroj: | GESD 2020-3rd International Conference on Green Energy and Sustainable Development GESD 2020-3rd International Conference on Green Energy and Sustainable Development, Nov 2020, Shenyang City, China. 7 p., ⟨10.1088/1755-1315/651/2/022001⟩ |
| ISSN: | 1755-1307 |
| Popis: | Biomass fast pyrolysis process is a technology that converts renewable solids into a dense liquid. This study aims to apprehend the thermodynamic behaviour of the Intermediate Liquid Compounds (ILCs) observed during the biomass fast pyrolysis. The system studied was a closed system (20 mL) with air and a mixture solution of five components (Acetic acid (AA), hydroxyacetone (HX), phenol; furfural (FF) and methanol) at 90°C and under atmospheric pressure. The flash calculation was conducted at a given temperature and pressure. The vapor-liquid equilibrium compositions were determined combining equation of state and activity coefficient models, the Soave-Redlich-Kwong (SRK) equation of state coupled with Modified Huron-Vidal (MHV2) mixing rules incorporating the UNIversal Functionnal Activity Coefficient (UNIFAC) model. Theoretical calculations of vapor-liquid equilibrium compositions were experimentally validated by using a Head-Space GC-MS system. A quantitative agreement between simulated and measured concentrations in the liquid phase was achieved with this combined state-predictive model of SRK-MHV2-UNIFAC model; thus, confirming that it accounts well for the nonidealities. |
| Databáze: | OpenAIRE |
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