Self-organizing surface-initiated polymerization, templated self-sorting and templated stack exchange: synthetic methods to build complex systems
| Autor: | Hironobu Hayashi, Raluca Turdean, Adam Sobczuk, Yingjie Zhao, Stefan Matile, Jetsuda Areephong, Marco Lista, Naomi Sakai, Edvinas Orentas, Alatengbaolige Bolag, Yuya Domoto, Adam Wilson, Giuseppe Sforazzini, Pierre Charbonnaz |
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| Rok vydání: | 2013 |
| Předmět: |
Models
Molecular Molecular Structure Surface Properties 010405 organic chemistry Chemistry Surface initiated Organic Chemistry Supramolecular chemistry Complex system Nanotechnology 010402 general chemistry 01 natural sciences Biochemistry Polymerization 0104 chemical sciences Self sorting Stack (abstract data type) ddc:540 Organic Chemicals Physical and Theoretical Chemistry |
| Zdroj: | Organic and Biomolecular Chemistry, Vol. 11, No 11 (2013) pp. 1754-1765 Organic and Biomolecular Chemistry |
| ISSN: | 1477-0539 1477-0520 |
| DOI: | 10.1039/c3ob27303b |
| Popis: | In nature spectacular function is achieved by highly sophisticated supramolecular architectures. Little is known what we would obtain if we could create complexity with similar precision because the synthetic methods to do so are not available. This account summarizes recent approaches conceived to improve on this situation. With self organizing surface initiated polymerization (SOSIP) charge transporting stacks can be grown directly on solid substrates with molecular level precision. The extension to templated self sorting (SOSIP TSS) offers a supramolecular approach to multicomponent architectures. A solid theoretical framework for the transcription of information by templated self sorting has been introduced intrinsic templation efficiencies up to 97 have been achieved and the existence of self repair has been shown. The extension to templated stack exchange (SOSIP TSE) offers the complementary covalent approach. Compatibility of this robust method with the creation of double channel architectures with antiparallel two component gradients has been demonstrated. © 2013 The Royal Society of Chemistry. |
| Databáze: | OpenAIRE |
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